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Thermodynamic study of tl6sbr4 compounds and some laws of thermodynamic properties of thallium chalcogenides

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Document pages: 9 pages

Abstract: According to the measurement results of electromotive force (EMF) of concentration cell relative to thallium electrode, the solid phase diagram of tl-tlbr-s system was clarified, and the basic thermodynamic properties of tl6sbr4 compound were studied. The EMF results are used to calculate the relative thermodynamic function of thallium in the alloy and the standard integral thermodynamic function of tl6sbr4 compound (, and). All data on thermodynamic properties of thallium halide chalcogenide elements are summarized and compared. Therefore, there is a certain regularity between the thermodynamic function of thallium sulfur halide and its binary fraction and the degree of ionization (DI) of chemical bond.

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