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Effects of fiber loading and porosity on tensile properties of keratin based randomly oriented human hair fiber composites

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https://www.eduzhai.net International Journal of Composite Materials 2017, 7(5): 136-143 DOI: 10.5923/j.cmaterials.20170705.02 Effect of Fiber Loading and Void Content on Tensile Properties of Keratin Based Randomly Oriented Human Hair Fiber Composites P. Divakara Rao1,*, C. Udaya Kiran1, K. Eshwara Prasad2 1Department of Mechanical Engineering, J.B. Institute of Engineering and Technology, Hyderabad, Telangana, India 2Department of Mechanical Engineering, Jawaharlal Nehru Technological University, Hyderabad, Telangana, India Abstract Human hair is a non-biodegradable waste available in abundant quantity across the world, but is not explored fully for applications in engineering field. Tensile strength of human hair ranges from 150 to 220 MPa. This property of human hair can be made use in the field of making bio-composites. In the present work, hair based bio-composites are prepared by combining the human hair and polyester using hand layup technique. Volume fraction of the human hair fiber is varied by fixing the fibre length at 20 mm and tensile tests were conducted as per the standards. While increasing the fibre volume fraction up to a certain range the composite materials have shown superior amendments in their tensile properties. Further, the experimental results are compared with theoretical models. Keywords Polyester resin, Human Hair Fiber, Bio-composite, Theoretical model 1. Introduction Renewable animal fibers provide an exciting opportunity to develop sustainable bio - composite materials. Nowadays, attention of researchers has been increased on these animal fiber reinforced composites due to their easy availability, light weight, low cost and eco-friendly nature. Research on animal fiber based composites is meagre, though, good amount of research is carried on plant based natural fibers. Chicken Feather, human hair and hairs of other birds and animal are commonly described as a waste by-product. Currently available disposal methods such as burying and burning of this waste by products are contributing to environmental pollution [1]. Human hair by nature is a fibrous material with good tensile properties. The primary component of the hair fiber is keratin which consists of proteins and long chains (polymers) of amino acids [2]. Cortex in the hair fiber is primarily responsible for the tensile properties of human hair [3]. Unlike other natural fibers, animal fibers are very complex in nature as their properties vary with many factors. Physical, chemical and mechanical properties of the animal fibers depend largely on the region, age and location of the fiber on the animal. Qiang Xiao et al. have studied the tensile properties of human hair fibers of different regions and ages of women [4]. Nwigbo S. C et al. * Corresponding author: raodivakar_p@yahoo.co.in (P. Divakara Rao) Published online at https://www.eduzhai.net Copyright © 2017 Scientific & Academic Publishing. All Rights Reserved has studied the mechanical properties of female African human hair reinforced polypropylene composites [5]. It offers much more effective solution for environmental pollution issues, If these hair fibers are successfully impregnated in resins to make composites and are used for various applications,. Presently human hair composites are being used in the areas of construction, automobiles and moulded furniture [6]. Thomson has patented his work on manufacturing of hair based composites [7]. Elanchezhian et al. in their research found that composites made of human hair are close to that of silk fiber made composites which are costly when compared to the former [8]. Krystyna Wrześniewska-Tosik et al. have proved in their research that addition of keratin into cellulose has improved hygroscopic properties. They further showed the improvement of biodegradability of cellulose- keratin fibers than that of cellulose fibers [9]. Both human hair and chicken feather are naturally made out of keratin, reports on human hair based composites is relatively merger. Keratin is the primary constituent of Human Hair fiber. These keratins are proteins, polymers of amino acids. Keratin proteins form the cytoskeleton of all epidermal cells. Keratin proteins comprise 65-95% of the total hair fiber by weight. Mostly hair fibers are made of hard keratins which do not dissolve in water. Hard keratins are highly resistant to proteolytic enzymes. Hair fiber durability and resistance to degradation under environmental stress comes from the linkage between the cystine molecules and keratin proteins that form disulfide chemical bonds. These bonds are very strong. Amino acids with their quantities present in normal International Journal of Composite Materials 2017, 7(5): 136-143 137 hair fiber are shown table 1. The hair is composed of raw elements which are shown in Table 2. Other element that are present in the hair in trace amounts are magnesium, arsenic, iron, chromium and other metals and minerals [10, 11]. Table 3. Experimental results of a single Human Hair fiber Average Diameter (μm) 80 Average breaking load (N) 0.80079 % elongation at break (GPa) 30.54 Table 1. Amino acids present in normal human hair [10, 11] Amino Acid Cysteine Serine Glutamic acid Threonine Glycine Leucine Valine Arginine Aspartic acid Alanine Proline Isoleucine Tyrosine Phenylalanine Histidine Methionine Amount in residues extracted 17.5 11.7 11.1 6.9 6.5 6.1 5.9 5.6 5 4.8 3.6 2.7 1.9 1.4 0.8 0.5 Table 2. Raw elements present in Hair [10, 11] Element Name Carbon Oxygen Nitrogen Hydrogen Sulphur Quantity 50.65% 20.85% 17.14% 6.36% 5% Figure 2. Stress –strain curve of Human hair fiber Various mechanical properties of normal human hair fiber reported in [12] are shown in table 4. Table 4. Properties of Human Hair fiber [9] Density, g/cm3 1.34 Tensile Strength (MPa) 150-200 Young’s Modulus (GPa) 1.74 – 4.15 Poisson’s ratio 0.36 - 0.39 2. Mechanism Involved in Randomly Oriented Discontinuous Fiber Composites A typical Hair fiber and its parts are shown in figure 1. Figure 1. Parts of Hair fiber A tension test on the single hair fibre is conducted on ten hair samples and the average value of these ten results are presented in table 3. The Stress strain diagram for typical south Indian women hair is shown in fig.2. Figure 3. Representation of (a) aligned discontinuous fibers (b) Random oriented discontinuous fibers The usage of discontinuous fibers in commercial applications is increasing day-by-day, though the reinforcement efficiency for discontinuous fibers is lower when compared to continuous fibers. Animal fibers are mostly available in short form only. Chopped glass fibers are extensively used in many applications. Short fiber composites can be produced with 90% of elasticity Modulus and 50% of tensile strength when compared to continuous fiber composites. Anisotropy is exhibited by the aligned fibrous composites there by giving maximum strength and 138 P. Divakara Rao et al.: Effect of Fiber Loading and Void Content on Tensile Properties of Keratin Based Randomly Oriented Human Hair Fiber Composites reinforcement along the alignment direction, where as fiber reinforcement is nonexistent in the transverse direction leading to low tensile stresses. However, Isotropic mechanical properties are exhibited by the randomly oriented short fiber composites. Applications involving multidirectional stresses normally use randomly oriented discontinuous fibers. The reinforcement efficiency for this case is only one-fifth that of an aligned fiber composite. Normally, short and discontinuous fibers are employed when the fiber orientation is random. Reinforcement of such fibers is shown in fig.3. 3. Methods 3.1. Predictive Models The mechanical properties such as tensile modulus and strength can be expressed in terms of properties and arrangements of constituent fibers and matrix material using the micromechanical analysis. The strength and modulus of a long continuous fiber reinforced composite can be predicted by (1), (2) from rule of mixtures: σ c =σ f V f + σ mVm (1) Ec = E f V f + EmVm (2) Where, σ c , σ f and σ m are stresses in composite, fiber and matrix respectively and Ec , E f and Em are Young’s modulus in composite, fiber and matrix respectively. V f , Vm represent the Volume fraction of the fibers and matrix material respectively. The correlation derived by the Puck is verified by Manera [13] in his research with equation (3): E11 = Em [3.92V f +0.89] (3) The strength of Calcium carbonate reinforced poly vinyl acetate matrix composite is verified by a polynomial model given in (4) suggested by V.Kavacevic [14] in terms of volume fraction of fiber and strength of matrix: σc =σ m (1-a aφ b f + cφ d f ) (4) The constants a, b, c, d can be obtained from experimentation and φ f represents the volume fraction of the fiber. Reduction in property in case of short fiber random oriented composites is due to the combined effect of reduced length of reinforcement fiber and different orientation of fibers in the matrix material. Stress distribution along a short fiber in fiber reinforced plastic composite is studied by Choon [15]. The Choon’s model for the Young’s modulus is considered as a modification of rule of mixtures and is given in (5): E11 = v f E f (1+ 1+(E f R / R2) Em ) +[1− v f (1 + R)]Em (5) Where, R is a geometric factor that depends on the fiber length and fiber orientation. Cox model is reviewed by Crawford [16] for predicting modulus of randomly distributed fiber in terms of longitudinal and transverse modulus as given in (6): E = 3 8 E1 + 5 8 E2 (6) Blumentritt, B. F. et al. [17] have proposed a model to estimate the ultimate strength and Young’s modulus of the composite in the plane of the fibers using (7) & (8): σuc = Kσσuf Vf + σm(1-Vf) (7) Ec = KEEfVf + Em(1 – Vf) (8) A. A. Shaikh and S.A. Channiwala [18] has proposed a predictive model through (9) to (11) to evaluate modulus in terms of weightage factors W1 W2 for fiber and matrix, respectively as: Ec = E f V f W1 + EmVmW2 (9) Ec =Vf [A] +B (10) Ec == Em [aVf+b] (11) The terms A and B are calculated using method of least squares. The model is verified with jute polyester short random fiber composite with an accuracy of 0.15%. The constants a and b in eq.11 are found to be 63.06 and 11.28 respectively for the volume fraction range of 12% to 25%. 3.2. Experimental Hair fibers cut into 20mm length and is uniformly spread in the mould. The polyester resin along with the catalyst and accelerators in required quantities are mixed thoroughly as per the standard procedure and poured in to the cleaned mould. Sufficient care is taken to have uniform distribution and full impregnation of fiber in the resin. The mould is then closed with other half part of mould, clamped tightly and is kept for 24 hours at room temperature as polyester cures completely in 24 hours of time. The composite sample sheets are fabricated with different fiber weight ratios. S.No 1 2 3 4 5 6 7 Table 5. Test Specimen data Test specimen code 20HHRC05 20HHRC10 20HHRC15 20HHRC20 20HHRC25 20HHRC30 20HHRC35 Weight ratio of hair fiber (%) 5.07 10.04 15.58 20.50 25.80 31.86 36.20 Weight ratio of Polyester (%) 94.93 89.96 84.42 79.5 74.2 68.14 63.8 International Journal of Composite Materials 2017, 7(5): 136-143 139 Test specimens are cut from the completely cured composite sheet as per ASTM standards D638-01 is shown in the figure 4a. Different sample and their composition are shown in table 5. The tensile tests are carried out using Autograph AG15, Shimazdu 0-50 kN range with an accuracy of 0.1N. Five specimens are tested for each fiber volume fraction with 1.4 mm/min rate of loading. A specimen under test is shown in figure 4b. the fiber (intra fiber voids). Increasing the fiber volume fraction, further increases the formation of voids between the fibers (inter fiber voids) which may be because of resin flow dynamics. Vvoid =  ρcth − ρcex ρcth  X100 (14) Figure 5. Variation of Composite density with fiber Weight fraction Figure 4. Specimen (a) before testing (b) during testing 4. Results and Discussions 4.1. Composite Density and Void Content Random oriented Human hair fiber polyester composites have been produced with 20mm fiber length and seven different volume fractions. The fiber volume fraction and composite density are calculated using (12) and (13): Vf = ρmW f ρ f Wm + ρmW f ; Vm =1−V f (12) ρ c =   W ρ f f + Wm ρm  −1   (13) Where, V, W & ρ represent volume fraction, weight fraction and density respectively and subscripts f , m and c represent the fiber, matrix and composite respectively. Equation (13) assumes that there is no void volume in the composite. The variation of density with fiber volume fraction is depicted in figure 5. The density of the composite is observed to be increasing with increasing fiber volume fraction although the density the composite is less than density of fiber but more than the matrix material. Void volume fraction is estimated using the expression (14) and the variation of void content with fiber volume fraction is shown in figure 6. It is observed that void content is higher for greater fiber volume fraction which is also reported by Darshil U. Shah et al. [19]. This may be due to the fact that for low fiber volume fractions, voids generally form with in Figure 6. Variation of Void volume fraction with fiber volume fraction 4.2. Effect of Fiber Weight Fraction on the Tensile Strength Table 6 shows the values of tensile strength against the fiber volume fraction. Fig.7 shows the tensile stress behaviour for the composite manufactured from 20mm fiber lengths maintaining a constant fiber aspect ratio of nearly 250 over the entire range of human hair fiber volume fraction. The tensile stress is noticeably increasing with increase in fiber loading up to 17.73% and then decreases with further increase in fiber loading. This may be due to the fact that few fibers are present for low fiber weight fractions and the stresses in the composite are high enough to break the fibers. The broken fibers do not carry any load and these broken fibers can be regarded as an array of aligned holes. As explained in composite theory [20], the reinforcing action of the fiber is only effective once the fiber volume fraction exceeds the critical value. Ghosh et al. [21] explained the minimum and critical fiber volume fractions for short banana fiber reinforced vinyl–ester composite to be 15% and 25% respectively. However there is a maximum fiber content 140 P. Divakara Rao et al.: Effect of Fiber Loading and Void Content on Tensile Properties of Keratin Based Randomly Oriented Human Hair Fiber Composites beyond which the properties of the composite deteriorate [22, 23]. Table 6. Variation of Experimental Stress with fiber volume fraction and Void content Specimen Code 20HHRC05 20HHRC10 20HHRC15 20HHRC20 20HHRC25 20HHRC30 20HHRC35 Fiber Volume fraction (Vf), % 4.27 8.53 13.36 17.73 22.52 28.1 32.17 Volume Void content, % 7.01 7.74 12.20 7.70 13.42 21.42 21.09 Experimental stress(σc), MPa 9.08 14.2 18.58 23.5 18.9 16.41 10.38 In the present study, the tensile properties of the composite registered a clear decline beyond 17.73% fiber loading. It is observed that the increase of fiber volume fraction beyond 17.73% has resulted in poor wettability and increase in void content. Similar types of observations are made by Pan N. At higher fiber weight fractions, fiber to fiber spacing becomes so small that the stress transfer between the fiber and matrix becomes ineffective as explained by Pan N [24]. As higher volume fractions of fiber results in poor fiber-to-fiber spacing which results in poor wetting and improper impregnation of fibers due to insufficient resin entry between closely packed fibers results in poor transfer of stresses between adjacent fibers. In fig.8, it is interesting to note that the stress strain curve of the composite exhibits a non-linear response which is quite different from the conventional fiber reinforced composites that show a linear behaviour. DU Shah et al [19] have reported similar type of non linear behaviour of plant fiber reinforced composites. Figure 7. Effect of Fiber weight ratio on Tensile Strength of Human Hair Reinforced Polyester Composites Figure 8. Stress- strain curve of HHRC at fiber volume fraction of 17.73% International Journal of Composite Materials 2017, 7(5): 136-143 141 Specimen Code 20HHRC05 20HHRC10 20HHRC15 20HHRC20 20HHRC25 20HHRC30 20HHRC35 Experimental 3.58 3.67 3.95 3.95 3.72 3.02 1.76 Table 7. Young’s Modulus values of experimental and theoretical models Series Model 2.90 2.93 2.97 3.01 3.05 3.10 3.14 Parallel Model 2.89 2.92 2.95 2.98 3.02 3.06 3.09 Hirsch's Model 2.89 2.92 2.95 2.99 3.02 3.06 3.09 Young’s Modulus, GPa Einstein & Guth Model Modified Bowyer & Bader's Model 3.24 2.74 3.76 2.62 4.54 2.49 5.40 2.37 6.51 2.23 8.05 2.08 9.33 1.96 Cox krenchel Modell 2.74 2.62 2.48 2.35 2.22 2.06 1.94 Manera Model 2.84 3.14 3.48 3.79 4.13 4.52 4.81 Pan's Model 2.87 2.88 2.90 2.91 2.92 2.94 2.95 Modified rule of Mixtures 2.80 2.74 2.66 2.60 2.53 2.45 2.39 Figure 9. Comparison of Tensile Modulus for different models 4.3. Tensile Modulus Tensile Modulus of composites with different fiber volume fraction are obtained from the simple tension test. Various theoretical models have been used to estimate the Young’s modulus of the designed composite and are tabulated in Table 7. It is evident from the figure 9 that young’s modulus from the experiments is in good agreement with theoretical models. A note should be made here with regard to the sharp fall in experimental value of the tensile modulus beyond the fiber volume fraction of 17.73%. This is due to high void volume content observed over and above 17.73% fiber volume fractions. Santulli et al. [25] suggest that no drop in the mechanical properties of the composite due to void content below 3- 4%, but the effect of void content above 4% on the property value of the composite is significant. Similar observations are also found in [22, 26]. Low fiber efficiency is exhibited due to poor wettability as explained earlier. 5. Conclusions The effect of fiber volume fraction on physical properties (density, porosity) and tensile properties of a random oriented HHRC are investigated. Composites with low fiber volume fraction are prone to intra fiber voids and high fiber volume fractions are prone to inter fiber voids. High value of void content of 21.42% is observed at fiber volume fractions beyond 28%. The effect of fiber loading on tensile properties is studied and maximum tensile strength of 23.5 MPa is observed at 17.73% fiber volume fraction. Similar types of results are published by T. Subramani et al. [27] in their investigation on chicken feather reinforced composites. Tensile modulus is experimentally obtained and the results are validated using different theoretical models. Experimental results are in close agreement with the theoretical models below 17.73% volume fractions. However, sharp drop in experimental tensile modulus value is observed above 17.73 % because of presence of high void 142 P. Divakara Rao et al.: Effect of Fiber Loading and Void Content on Tensile Properties of Keratin Based Randomly Oriented Human Hair Fiber Composites volume content. Lesser void volume content has minimal effect on the tensile properties of the human hair reinforced polyester composites. The tensile strength and Tensile Modulus obtained for the composite in the present research are exhibiting reasonably superior values over composites made of Polyethylene reinforced with keratin fibers obtained from chicken feathers [28], random oriented, non woven short banana/Epoxy composite[29] and many more natural fiber composites. The present research was focussed on the use of abundantly available waste human hair as an alternative reinforcement for natural fiber composite materials. The cost and environmental benefits associated with the use of this new sustainable bio-composite material depends on the wide success. However several limitations must be overcome in order to exploit the full potential of human hair fibers. Proper fiber treatment that enhances fiber matrix bonding should be developed. Secondly, the use of hair mats should be investigated in order to get uniform distribution of fibers in the matrix material. REFERENCES [1] Uzun M, Sancak E, Patel I, Usta I, Akalın M, Yuksek M. Mechanical behaviour of chicken quills and chicken feather Fibers reinforced polymeric composites. Archives of Materials Science and Engineering. 2011; 52(2): 82-86. [2] Jolon Dyer and Anita Grosvenor. Protein Fiber Surface Modification, Natural Dyes, Dr. Emriye Akcakoca Kumbasar (Ed.), ISBN: 978-953-307-783-3, In Tech, 2011. [3] Robbins C R. Chemical and Physical Behaviour of Human Hair, 5th Edition, Springer-Verlag Berlin Heidelberg, New York, 2012. [4] Xiao et al., Nano Tensile Study Single Hum Hair Fiber, 2006. [5] Nwigbo S C, Atuanya C U, Ulasi O A. 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